James Franco, Ramin Karimloo, Andy Karl, and Jessie Mueller will also be on hand.
McDonald stars in Lanie Robertson's drama at the Circle in the Square Theatre.
The revival of the classic musical opened at the Imperial Theatre on March 23.
Step aside, Hugh Jackman and Ramin Karimloo.
The new production begins previews March 1 at the Imperial Theatre.
Original Jean Valjean Colm Wilkinson shared the stage with Karimloo in a Toronto performance of Les Misérables.
Meet the lovely ladies, factory workers, drunks, and soldiers who will appear in the musical at the Imperial Theatre.
The cast also includes the previously announced Ramin Karimloo, Will Swenson, Caissie Levy, and Nikki M. James.
Broadway's future Jean Valjean sings "Bring Him Home."